Syntheses and reactions of aluminum complexes of capped porphyrin
1990; Elsevier BV; Volume: 46; Issue: 3 Linguagem: Inglês
10.1016/s0040-4020(01)81358-2
ISSN1464-5416
Autores Tópico(s)Metal-Catalyzed Oxygenation Mechanisms
ResumoAl complexes of a capped porphyrin were newly synthesized with methyl, carboxylate, and phenoxide groups as axial ligands on the opposite side of the cap. (CapP)Al complexes undergo the exchange of the carboxylate or phenoxide group with carboxylic acid or phenol, respectively, much more slowly than the corresponding (TPP)Al complexes.
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