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Use of slurry sampling for the direct determination of zinc in yogurt by high resolution-continuum source flame atomic absorption spectrometry

2010; Elsevier BV; Volume: 81; Issue: 4-5 Linguagem: Inglês

10.1016/j.talanta.2010.02.033

1873-3573

Geovani C. Brandão, Raildo Mota de Jesus, Erik Galvão Paranhos da Silva, Sérgio L.C. Ferreira,

Pesticide Residue Analysis and Safety

This paper presents an analytical procedure for the direct determination of zinc in yogurt employing sampling slurry and high resolution-continuum source flame atomic absorption spectrometry (HR-CS FAAS). The step optimization established the experimental conditions of: 2.0 mol L−1 hydrochloric acid, a sonication time of 20 min and a sample mass of 1.0 g for a slurry volume of 25 mL. This method allows the determination of zinc with a limit of quantification of 0.32 μg g−1. The precision expressed as relative standard deviation (RSD) were 0.82 and 2.08% for yogurt samples containing zinc concentrations of 4.85 and 2.49 μg g−1, respectively. The accuracy was confirmed by the analysis of a certified reference material of non-fat milk powder furnished by the National Institute of Standard and Technology. The proposed method was applied for the determination of zinc in seven yogurt samples. The zinc content was varied from 2.19 to 4.85 μg g−1. These results agreed with those reported in the literature. The samples were also analyzed after acid digestion and zinc determination by FAAS. No statistical difference was observed between the results obtained by both of the procedures performed.