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The interaction of sulfenamide accelerators with sulfur, ZNO, and stearic acid in the absence of rubber

1994; Wiley; Volume: 51; Issue: 1 Linguagem: Inglês

10.1002/app.1994.070510118

1097-4628

M. H. S. Gradwell, W. J. McGill,

Thermal and Kinetic Analysis

Abstract The interaction of sulfur, ZnO, stearic acid, and the three sulfenamide accelerators N ‐cyclohexylbenzothiazole sulfenamide (CBS), 2‐(4‐morpholinothio) benzothiazole (MOR), and 2‐ t ‐butylaminobenzothiazole sulfenamide (TBBS) were investigated by differential scanning calorimetry in the absence of rubber. In the presence of sulfur, the same product spectrum is formed as in its absence, but at lower temperatures. Thus, CBS gives N ‐cyclohexylamino‐2‐benzothiazole polysulfides (CBP), 2‐bisbenzothiazole‐2,2′‐disulfide (MBTS), 2‐bisbenzothiazole‐2,2′‐polysulfides (MBTP), and 2‐bisbenzothiazole‐2,2′‐monosulfide (MBTP), 2‐mercaptobenzothiazole (MBT), and 2‐ N ‐cyclohexylaminobenzothiazole (CB). In the presence of sulfur, the amount of polysulfides formed initially is higher but the polysulfides are unstable, and on prolonged heating, only MBT and CB remain. MOR and TBBS form analogous product spectra. The sulfenamides do not react with ZnO or zinc stearate. The MBT–amine complex prevents MBT, formed on decomposition, from reacting to give zinc mercaptobenzothiazole (ZHBT). Reaction mechanisms are proposed to account for the formation of the products. © 1994 John Wiley & Sons, Inc.