Artigo Revisado por pares

Solubility of rhodochrosite (MnCO3) in water and seawater

1982; Elsevier BV; Volume: 46; Issue: 10 Linguagem: Inglês

10.1016/0016-7037(82)90119-3

ISSN

1872-9533

Autores

Kenneth S. Johnson,

Tópico(s)

Iron oxide chemistry and applications

Resumo

The solubility product of rhodochrosite (MnCO3) was measured in seawater, deionized water and dilute NaCl solutions. The solubility product extrapolated to infinite dilution at 25.0 C was (2.60 ± 0.07)× 10−11. The stoichiometric solubility product measured in seawater of 34.27%. salinity was (3.24 ± 0.23) × 10−9 at 25.0 C and (2.28 ± 0.24) × 10−9 at 3.3 C. The stoichiometric solubility product is in good agreement with the value calculated from an ion association model. The enthalpy of the reaction is in fair agreement with the estimated value.

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