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Enantioselective epoxidation of styrene derivatives by chloroperoxidase catalysis

1993; Elsevier BV; Volume: 4; Issue: 6 Linguagem: Inglês

10.1016/s0957-4166(00)80243-8

1362-511X

Stefano Colonna, Nicoletta Gaggero, Luigi Casella, Giacomo Carrea, Piero Pasta,

Metal-Catalyzed Oxygenation Mechanisms

Chloroperoxidase catalysed epoxidadon of styrene derivatives by t-BuOOH preferentially gives (R) oxides with ee values between 28 and 68%. The data support the view of oxygen delivery from the ferryl oxygen directly to the substrate.