Solvation of Palladium Diacetate in Trifluoroacetic Acid
1996; American Chemical Society; Volume: 100; Issue: 43 Linguagem: Inglês
10.1021/jp9621944
ISSN1541-5740
AutoresOle Swang, Richard Blom, Olav B. Ryan, Knut Fægri,
Tópico(s)Advanced Chemical Physics Studies
ResumoThe solvation of palladium diacetate in trifluoroacetic acid has been studied by ab initio quantum chemical calculations and infrared and NMR spectroscopy. We report evidence for the formation of a dicarboxylate−dicarboxylic acid species, with square planar coordination around the metal center, through addition of two acid molecules.
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