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Direct Stereospecific Amination of Alkyl and Aryl Pinacol Boronates

2012; American Chemical Society; Volume: 134; Issue: 40 Linguagem: Inglês

10.1021/ja305448w

1943-2984

Scott N. Mlynarski, Alexander S. Karns, James P. Morken,

Coordination Chemistry and Organometallics

The direct amination of alkyl and aryl pinacol boronates is accomplished with lithiated methoxyamine. This reaction directly provides aliphatic and aromatic amines, stereospecifically, and without preactivation of the boronate substrate.