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1,1,2,2‐Tetrakis(dimethylsilyl)‐1,2‐ethanediylithium‐bis(diethyl ether):Observation of a SiHLi Agostic Interaction

1997; Wiley; Volume: 36; Issue: 13-14 Linguagem: Inglês

10.1002/anie.199715331

ISSN

1521-3773

Autores

Akira Sekiguchi, Masaaki Ichinohe, T. Takahashi, Chizuko Kabuto, Hideki Sakurai,

Tópico(s)

Crystallography and molecular interactions

Resumo

Structural and sepectroscopic properties for the title compound 2 provide clear evidence for a SiHLi agostic interaction. Compound 2 was prepared by the reaction of tetrakis(dimethylsilyl)ethene (1) with lithium metal in ether.

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