Hexakis(but‐3‐ynyl)benzene
1996; Wiley; Volume: 35; Issue: 15 Linguagem: Turco
10.1002/anie.199617011
ISSN1521-3773
AutoresHans‐W. Marx, Françoise Moulines, Trixie Wagner, Didier Astruc,
Tópico(s)Molecular Sensors and Ion Detection
ResumoAngewandte Chemie International Edition in EnglishVolume 35, Issue 15 p. 1701-1704 Communication Hexakis(but-3-ynyl)benzene† Dr. Hans-W. Marx, Dr. Hans-W. Marx Laboratoire de Chimie Organique et Organométallique URA CNRS No. 35, Université Bordeaux I 351, Cours de la Libération, F-33405 Talence Cédex (France) Fax: Int. code +(56)846646 e-mail: astruc@cribx1.u-bordeaux.frSearch for more papers by this authorDr. Françoise Moulines, Dr. Françoise Moulines Laboratoire de Chimie Organique et Organométallique URA CNRS No. 35, Université Bordeaux I 351, Cours de la Libération, F-33405 Talence Cédex (France) Fax: Int. code +(56)846646 e-mail: astruc@cribx1.u-bordeaux.frSearch for more papers by this authorDr. Trixie Wagner, Dr. Trixie Wagner Institut für Anorganische Chemie der Technischen Hochschule Professor-Pirlet-Strasse 1, D-52074 Aachen (Germany)Search for more papers by this authorProf. Didier Astruc, Corresponding Author Prof. Didier Astruc Laboratoire de Chimie Organique et Organométallique URA CNRS No. 35, Université Bordeaux I 351, Cours de la Libération, F-33405 Talence Cédex (France) Fax: Int. code +(56)846646 e-mail: astruc@cribx1.u-bordeaux.frLaboratoire de Chimie Organique et Organométallique URA CNRS No. 35, Université Bordeaux I 351, Cours de la Libération, F-33405 Talence Cédex (France) Fax: Int. code +(56)846646 e-mail: astruc@cribx1.u-bordeaux.frSearch for more papers by this author Dr. Hans-W. Marx, Dr. Hans-W. Marx Laboratoire de Chimie Organique et Organométallique URA CNRS No. 35, Université Bordeaux I 351, Cours de la Libération, F-33405 Talence Cédex (France) Fax: Int. code +(56)846646 e-mail: astruc@cribx1.u-bordeaux.frSearch for more papers by this authorDr. Françoise Moulines, Dr. Françoise Moulines Laboratoire de Chimie Organique et Organométallique URA CNRS No. 35, Université Bordeaux I 351, Cours de la Libération, F-33405 Talence Cédex (France) Fax: Int. code +(56)846646 e-mail: astruc@cribx1.u-bordeaux.frSearch for more papers by this authorDr. Trixie Wagner, Dr. Trixie Wagner Institut für Anorganische Chemie der Technischen Hochschule Professor-Pirlet-Strasse 1, D-52074 Aachen (Germany)Search for more papers by this authorProf. Didier Astruc, Corresponding Author Prof. Didier Astruc Laboratoire de Chimie Organique et Organométallique URA CNRS No. 35, Université Bordeaux I 351, Cours de la Libération, F-33405 Talence Cédex (France) Fax: Int. code +(56)846646 e-mail: astruc@cribx1.u-bordeaux.frLaboratoire de Chimie Organique et Organométallique URA CNRS No. 35, Université Bordeaux I 351, Cours de la Libération, F-33405 Talence Cédex (France) Fax: Int. code +(56)846646 e-mail: astruc@cribx1.u-bordeaux.frSearch for more papers by this author First published: August 1996 https://doi.org/10.1002/anie.199617011Citations: 36 † Financial support from the Institut Universitaire de France, the Region Aquitaine, the CNRS, the Université Bordeaux I, and the DAAD (NATO grant to H.-W. M.) is gratefully acknowledged. We thank Dr S. Moss for the force-field calculations. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract The twelvefold dehydrobromination provides the title compound 1 in a straightforward, easily reproducible synthesis. In the solid state 1 displays a well-defined structure with Ci symmetry, in which four of the the six branches assume trans and two assume gauche arrangements. Compound 1, which can be stannylated, deprotonated, and complexed, should be a useful intermediate in the preparation of dendritic structures. Citing Literature Volume35, Issue15August 1996Pages 1701-1704 RelatedInformation
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