A mononuclear copper(II) complex of an unsymmetrical dinucleating ligand
1995; Royal Society of Chemistry; Issue: 11 Linguagem: Inglês
10.1039/dt9950001883
ISSN2050-5671
AutoresHarry Adams, Neil A. Bailey, David E. Fenton, George Papageorgiou,
Tópico(s)Metal-Catalyzed Oxygenation Mechanisms
ResumoThe unsymmetrical and potentially dinucleating ligand 4-bromo-2-(2-hydroxyethyliminomethyl)-6-(morpholin-4-ylmethyl)phenol (H2L1) has been prepared via a Mannich reaction under non-aqueous aprotic conditions. Reaction with copper(II) yielded mono- and di-nuclear complexes; the crystal structure of the mononuclear complex [Cu(H2L1)][CIO4]2·H2O·MeOH has been determined.
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