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Residual Dipolar Coupling Enhanced NMR Spectroscopy and Chiroptics: A Powerful Combination for the Complete Elucidation of Symmetrical Small Molecules

2011; Wiley; Volume: 17; Issue: 43 Linguagem: Inglês

10.1002/chem.201101385

1521-3765

Carlos Pérez‐Balado, Han Sun, Christian Griesinger, Ángel R. de Lera, Armando Navarro‐Vázquez,

Spectroscopy and Quantum Chemical Studies

Chemistry – A European JournalVolume 17, Issue 43 p. 11983-11986 Communication Residual Dipolar Coupling Enhanced NMR Spectroscopy and Chiroptics: A Powerful Combination for the Complete Elucidation of Symmetrical Small Molecules Dr. Carlos Pérez-Balado, Dr. Carlos Pérez-Balado Departamento de Química Orgánica, Universidade de Vigo, 36310, Vigo (Spain)Search for more papers by this authorHan Sun, Han Sun Department of NMR-Based Structural Biology, Max Planck Institute for Biophysical Chemistry (MPIbpc), D-30777 Göttingen (Germany)Search for more papers by this authorProf. Christian Griesinger, Prof. Christian Griesinger Department of NMR-Based Structural Biology, Max Planck Institute for Biophysical Chemistry (MPIbpc), D-30777 Göttingen (Germany)Search for more papers by this authorProf. Ángel R. de Lera, Corresponding Author Prof. Ángel R. de Lera [email protected] Departamento de Química Orgánica, Universidade de Vigo, 36310, Vigo (Spain)Departamento de Química Orgánica, Universidade de Vigo, 36310, Vigo (Spain)Search for more papers by this authorDr. Armando Navarro-Vázquez, Corresponding Author Dr. Armando Navarro-Vázquez [email protected] Departamento de Química Orgánica, Universidade de Vigo, 36310, Vigo (Spain)Departamento de Química Orgánica, Universidade de Vigo, 36310, Vigo (Spain)Search for more papers by this author Dr. Carlos Pérez-Balado, Dr. Carlos Pérez-Balado Departamento de Química Orgánica, Universidade de Vigo, 36310, Vigo (Spain)Search for more papers by this authorHan Sun, Han Sun Department of NMR-Based Structural Biology, Max Planck Institute for Biophysical Chemistry (MPIbpc), D-30777 Göttingen (Germany)Search for more papers by this authorProf. Christian Griesinger, Prof. Christian Griesinger Department of NMR-Based Structural Biology, Max Planck Institute for Biophysical Chemistry (MPIbpc), D-30777 Göttingen (Germany)Search for more papers by this authorProf. Ángel R. de Lera, Corresponding Author Prof. Ángel R. de Lera [email protected] Departamento de Química Orgánica, Universidade de Vigo, 36310, Vigo (Spain)Departamento de Química Orgánica, Universidade de Vigo, 36310, Vigo (Spain)Search for more papers by this authorDr. Armando Navarro-Vázquez, Corresponding Author Dr. Armando Navarro-Vázquez [email protected] Departamento de Química Orgánica, Universidade de Vigo, 36310, Vigo (Spain)Departamento de Química Orgánica, Universidade de Vigo, 36310, Vigo (Spain)Search for more papers by this author First published: 16 September 2011 https://doi.org/10.1002/chem.201101385Citations: 20Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Absolute configuration assignment: Residual dipolar coupling (RDC)-enhanced NMR spectroscopy provides detailed configurational and conformational information on a symmetric homodimeric chiral organic compound. This allows unequivocal assignment of absolute configuration by using electronic circular dichroism and time-dependent (TD)-DFT computations. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description chem_201101385_sm_miscellaneous_information.pdf689.6 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume17, Issue43October 17, 2011Pages 11983-11986 RelatedInformation