Novel zirconium complexes of amine bis(phenolate) ligands. Remarkable reactivity in polymerization of hex-1-ene due to an extra donor arm
2000; Royal Society of Chemistry; Issue: 5 Linguagem: Inglês
10.1039/b000396o
ISSN1364-548X
AutoresEdit Y. Tshuva, Israel Goldberg, Moshe Kol, Hana Weitman, Zeev Goldschmidt,
Tópico(s)Carbon dioxide utilization in catalysis
ResumoZirconium complexes of two dianionic amine bis(phenolate) ligands have been synthesized, their X-ray structures solved, and their activity as hex-1-ene polymerization catalysts studied; upon treatment with B(C6F5)3, an octahedral [ONNO]Zr(CH2Ph)2 complex, having an extra N-donor group on a side arm, shows exceptionally high polymerization activity and yields a high molecular weight poly(hex-1-ene), whereas a related pentacoordinate [ONO]Zr(CH2Ph)2 complex, having no extra donor group, shows only poor activity as a polymerization catalyst.
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