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Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2000

2005; Elsevier BV; Volume: 249; Issue: 24 Linguagem: Inglês

10.1016/j.ccr.2005.03.001

1873-3840

Ji‐Young Hyeon, J. Gottfriedsen, Frank T. Edelmann,

Coordination Chemistry and Organometallics

Ligands containing π-systems are common throughout main group and transition metal chemistry; but have also found significant use in the organometallic chemistry of the f-block elements. Due to the high degree of coordinative saturation, the cyclopentadienyl and phospholyl ligand sets are ideal for the stabilization of compounds containing f-block elements. Cyclopentadienyl and its substituted derivatives have contributed greatly to the overall development of the discipline, with the steric and electronic modularity of the ligand offering great insight into both structure and reactivity.