The molecular and solid‐state structure of borazine has been determined at 115 and 160 K by single‐crystal X‐ray crystallography. The molecular structure has C 2 symmetry with small deviations from the expected D 3 h symmetry. The mean value of the BN bond length is 1.429(1) A and the interbond angles of the six‐membered ring are 117.1(1)° at the boron atoms and 122.9(1)° at the nitrogen atoms (mean values). Similar to benzene an unambiguous assignment of…

1994; Wiley; Volume: 127; Issue: 10 Linguagem: Alemão

10.1002/cber.19941271011

ISSN

0009-2940

Autores

Roland Boese, Andreas H. Maulitz, Peter Stellberg,

Tópico(s)

Synthesis and characterization of novel inorganic/organometallic compounds

Resumo

Borazin im festen Zustand: Verdient es, als “anorganisches Benzol” bezeichnet zu werden?

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