13C and195Pt NMR ofpara-substitutedN,N-dialkyl-N′-benzoylthioureas and theircis-[ML2] complexes, M = Pd(II) and Pt(II)
1991; Wiley; Volume: 29; Issue: 11 Linguagem: Inglês
10.1002/mrc.1260291114
ISSN1097-458X
AutoresKlaus R. Koch, Mangaka C. Matoetoe,
Tópico(s)Magnetism in coordination complexes
ResumoAbstract A series of neutral cis ‐[ML 2 ] complexes, where M = Pd(II) and Pt(II) and L = para ‐substituted N , N ‐dialkyl‐ N ′‐benzoyl‐thio‐urea anion, were examined by means of 13 C and 195 Pt NMR. Unambiguous assignment of the thiocarbonyl carbon atom in these complexes was achieved with 13 C isotopic enrichment and the resolved n J ( 195 Pt, 13 C) coupling satellites.
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