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Hyper-dendritic nanoporous zinc foam anodes

2015; Nature Portfolio; Volume: 7; Issue: 4 Linguagem: Inglês

10.1038/am.2015.32

1884-4057

Mylad Chamoun, Benjamin Hertzberg, Tanya Gupta, Daniel R. Davies, Shoham Bhadra, Barry Van Tassell, Can K. Erdonmez, Daniel A. Steingart,

Advanced Battery Materials and Technologies

The low cost, significant reduction potential and relative safety of the zinc electrode is a common hope for a reductant in secondary batteries, but it is limited mainly to primary implementation due to shape change. In this work, we exploit such shape change for the benefit of static electrodes through the electrodeposition of hyper-dendritic nanoporous zinc foam. Electrodeposition of zinc foam resulted in nanoparticles formed on secondary dendrites in a three-dimensional network with a particle size distribution of 54.1–96.0 nm. The nanoporous zinc foam contributed to highly oriented crystals, high surface area and more rapid kinetics in contrast to conventional zinc in alkaline mediums. The anode material presented had a utilization of ~88% at full depth-of-discharge (DOD) at various rates indicating a superb rate capability. The rechargeability of Zn0/Zn2+ showed significant capacity retention over 100 cycles at a 40% DOD to ensure that the dendritic core structure was imperforated. The dendritic architecture was densified upon charge–discharge cycling and presented superior performance compared with bulk zinc electrodes. A synthetic method turns a problem with plate metal batteries into a path for greater stability and may lead to safer, cheaper batteries. Zinc is more abundant and easier to handle than lithium, but electrodes made from it suffer from shape-change effects that prevent stable cycling. Now, by electrodepositing nanoporous zinc foam onto a traditional current collector, Daniel Steingart from Princeton University in the USA and colleagues have exploited a problem with zinc electrodes — the formation of dendritic crystals that can short-circuit batteries. The team broke convention by deliberately conditioning their zinc electrodes at potentials far from equilibrium. This created a hyper-dendritic network foam that forms with 88% current efficiency and remains stable for over 100 recharge cycles — results superior to those of conventional batteries with non-porous zinc electrodes. The low cost, significant reduction potential and relative safety of the zinc electrode is a common hope for a reductant in secondary batteries, but it is limited mainly to primary implementation due to shape change. In this work, we exploit such shape change for the benefit of static electrodes through the electrodeposition of hyper-dendritic nanoporous zinc foam. Electrodeposition of zinc foam resulted in nanoparticles formed on secondary dendrites in a three-dimensional network with a particle size distribution of 54.1–96.0 nm. The nanoporous zinc foam contributed to highly oriented crystals, high surface area and more rapid kinetics in contrast to conventional zinc in alkaline mediums. The anode material presented had a utilization of ~88% at full depth-of-discharge (DOD) at various rates indicating a superb rate capability. The rechargeability of Zn0/Zn2+ showed significant capacity retention over 100 cycles at a 40% DOD to ensure that the dendritic core structure was imperforated. The dendritic architecture was densified upon charge–discharge cycling and presented superior performance compared with bulk zinc electrodes.