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A new procedure for the synthesis of D -glucosamine α-C-glycosides

1989; Royal Society of Chemistry; Issue: 5 Linguagem: Inglês

10.1039/c39890000297

2050-5639

Marta Carcano, Francesco Nicotra, Luigi Panza, Giovanni Russo,

Biopolymer Synthesis and Applications

Reaction of (2,3,5-tri-O-benzyl-D-arabinofuranosyl)benzylamine with vinylmagnesium bromide and subsequent mercuriocyclisation of the obtained open-chain product, provides a stereoselective entry to α-C-glycosides of D-glucosamine.