Synthetic and structural studies on Group 13 complexes containing the M(CO) 3 (η-C 5 H 5 ) fragment (M = Cr or Mo). Part 2. Complexes [InCl x {M(CO) 3 (η-C 5 H 5 )} 2 ] n

Artigo

Synthetic and structural studies on Group 13 complexes containing the M(CO) 3 (η-C 5 H 5 ) fragment (M = Cr or Mo). Part 2. Complexes [InCl x {M(CO) 3 (η-C 5 H 5 )} 2 ] n– (x= 1, n= o; x= 2, n= 1)

1991; Royal Society of Chemistry; Issue: 9 Linguagem: Inglês

10.1039/dt9910002241

ISSN

2050-5671

Autores

Lucy M. Clarkson, W. Clegg, David C. R. Hockless, Nicholas C. Norman, Louis J. Farrugia, Simon G. Bott, Jerry L. Atwood,

Tópico(s)

Organoboron and organosilicon chemistry

Resumo

The synthesis and solution infrared studies of a range of compounds of general formula [InX(L){M(CO)3(η-C5H5)}2] have been performed where X = Cl or I, L = X, tetrahydrofuran (thf), pyridine (py) and M = Cr, Mo or W. In addition, structures have been determined by X-ray analysis for [InCl(thf){Mo(CO)3(η-C5H5)}2], [InCl(py){Cr(CO)3(η-C5H5)}2] and [NMe4][InCl2{Mo(CO)3(η-C5H5)}2] and these are discussed and compared with the structures of related complexes.

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Synthetic and structural studies on Group 13 complexes containing the M(CO) 3 (η-C 5 H 5 ) fragment (M = Cr or Mo). Part 2. Complexes [InCl x {M(CO) 3 (η-C 5 H 5 )} 2 ] n– (x= 1, n= o; x= 2, n= 1)