Formation of Unusual Iridabenzene and Metallanaphthalene Containing Electron-Withdrawing Substituents
2003; American Chemical Society; Volume: 125; Issue: 33 Linguagem: Inglês
10.1021/ja035655p
ISSN1943-2984
AutoresMargarita Paneque, C.M. Posadas, Manuel L. Poveda, Nuria Rendón, Verónica Salazar, Enrique Oñate, K. Mereiter,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoA new route to irida-aromatic derivatives which consists of the oxidation of bicyclic compounds has been disclosed. The iridanaphthalene 3 experiences hydrolytic cleavage of the Ir-carboxylate moiety regenerating the bicyclic structure 5, whereas treatment of 5 with ClC(O)CO2Me yields back the metalla-aromatic 3.
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