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Artigo Revisado por pares
BIBTEX RIS

The direct formation of ketones by reaction of methyl- and aryl-(carbonyl)(iodo)pentamethylcyclopentadienylrhodium complexes with organic iodides

1987; Elsevier BV; Volume: 330; Issue: 3 Linguagem: Inglês

10.1016/s0022-328x(00)99063-6

ISSN

1872-8561

Autores

Francesco Paolo Fanizzi, Glenn J. Sunley, Peter M. Maitlis,

Tópico(s)

Catalytic Cross-Coupling Reactions

Resumo

[C5Me5Rh(aryl)(CO)I] reacts with methyl iodide to give [(C5Me5RhI2)2] and arylCOMe; similar reactions occur between [C5Me5Rh(Me)(CO)I] and RI to give the ketones RCOMe (R = Ph, Me, Et, or Pr).

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