Oxidation of α,β-enones and alkenes with oxone and sodium halides: A convenient laboratory preparation of chlorine and bromine
1996; Elsevier BV; Volume: 37; Issue: 14 Linguagem: Inglês
10.1016/0040-4039(96)00295-x
ISSN1873-3581
AutoresR. Karl Dieter, Lois E. Nice, Sadanandan E. Velu,
Tópico(s)Oxidative Organic Chemistry Reactions
ResumoMixtures of oxone and sodium chloride or sodium bromide afford solutions of chlorine or bromine, respectively. These solutions effectively add chlorine and bromine to α,β-enones and alkenes. The method affords improved yields of 3-alkyl-2-halo-2-cycloalkenones which are sometimes difficult to prepare.
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