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Tetrahedral Zinc Blende Tin Sulfide Nano‐ and Microcrystals

2006; Wiley; Volume: 2; Issue: 3 Linguagem: Inglês

10.1002/smll.200500460

1613-6829

Eric C. Greyson, Jeremy Barton, Teri W. Odom,

2D Materials and Applications

SmallVolume 2, Issue 3 p. 368-371 Communication Tetrahedral Zinc Blende Tin Sulfide Nano- and Microcrystals† Eric C. Greyson, Eric C. Greyson Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA, Fax: (+1) 847-491-7713Search for more papers by this authorJeremy E. Barton, Jeremy E. Barton Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA, Fax: (+1) 847-491-7713Search for more papers by this authorTeri W. Odom Prof., Teri W. Odom Prof. [email protected] Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA, Fax: (+1) 847-491-7713Search for more papers by this author Eric C. Greyson, Eric C. Greyson Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA, Fax: (+1) 847-491-7713Search for more papers by this authorJeremy E. Barton, Jeremy E. Barton Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA, Fax: (+1) 847-491-7713Search for more papers by this authorTeri W. Odom Prof., Teri W. Odom Prof. [email protected] Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA, Fax: (+1) 847-491-7713Search for more papers by this author First published: 30 January 2006 https://doi.org/10.1002/smll.200500460Citations: 166 † This research was supported by an NSF CAREER Award (CHE-0349302). This work made use of the NUANCE Center facilities, which are supported by NSF-MRSEC, NSF-NSEC, Keck Foundation and Northwestern University. We thank Prof. Art Freeman and S.H. Rhim for performing electronic band structure calculations on the ZB SnS crystal structure. T.W.O. is an Alfred P. Sloan Research Fellow, a Cottrell Scholar of Research Corporation, a DuPont Young Professor, and a David and Lucile Packard Fellow. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Entering a new phase: Tin sulfide (SnS) nano- and microcrystals were synthesized by a seedless, solution procedure. Three-dimensional tetrahedral particles crystallized in the zinc blende (ZB) structure (see SEM image) while two-dimensional platelike particles crystallized in the orthorhombic phase. The optical properties of the orthorhombic plates were similar to bulk SnS, but the absorption edge of the ZB tetrahedra was blue-shifted by around 300 nm compared to that of bulk SnS. References 1R. Hoffman, Angew. Chem. 1987, 99, 871; Angew. Chem. Int. Ed. Engl. 1987, 26, 846. 2T. Hyeon, Chem. Commun. 2003, 8, 927. 3C. B. Murray, S. Sun, W. Gaschler, H. Doyle, T. A. Betley, C. R. Kagan, IBM J. Res. Dev. 2001, 45, 47. 4T. Trindade, P. O'Brien, N. L. Pickett, Chem. Mater. 2001, 13, 3843. 5L. Qu, X. Peng, J. Am. Chem. Soc. 2002, 124, 2049. 6P. D. Cozzoli, L. Manna, M. L. Curri, S. Kudera, C. Giannini, M. Striccoli, A. Agostiano, Chem. Mater. 2005, 17, 1296. 7S. C. Erwin, Z. Lu, M. I. Haftel, A. L. Efros, T. A. Kennedy, D. J. Norris, Nature 2005, 436, 91. 8J. B. Johnson, H. Jones, B. S. Latham, J. D. Parker, R. D. Engelken, C. Barber, Semicond. Sci. Technol. 1999, 14, 501. 9Y. Zhao, Z. Zhang, H. Dang, W. Liu, Mater. Sci. Eng. B 2004, 113, 175. 10C. An, K. Tang, Y. Jin, Q. Liu, X. Chen, Y. Qian, J. Cryst. Growth 2003, 252, 581. 11D. Chen, G. Z. Shen, K. B. Tang, S. J. Lei, H. G. Zheng, Y. T. Qian, J. Cryst. Growth 2004, 260, 469. 12S. B. Badachhape, A. Goswami, J. Phys. Soc. Jpn. 1962, 17, 251. 13A. N. Mariano, K. L. Chopra, Appl. Phys. Lett. 1967, 10, 282. 14L. Manna, E. C. Scher, A. P. Alivisatos, J. Am. Chem. Soc. 2000, 122, 12700. 15L. Manna, D. J. Milliron, A. Meisel, E. C. Scher, A. P. Alivisatos, Nat. Mater. 2003, 2, 382. 16M. Chen, Y. Xie, J. Lu, Y. Xiong, S. Zhang, Y. Qian, X. Liu, J. Mater. Chem. 2002, 12, 748. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2296/2006/z500460_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume2, Issue3March 2006Pages 368-371 ReferencesRelatedInformation