CH4 storage and CO2 capture in highly porous zirconium oxide based metal–organic frameworks
2012; Royal Society of Chemistry; Volume: 48; Issue: 79 Linguagem: Inglês
10.1039/c2cc34714h
ISSN1364-548X
AutoresQingyuan Yang, Vincent Guillerm, Florence Ragon, Andrew D. Wiersum, Philip L. Llewellyn, Chongli Zhong, Thomas Devic, Christian Serre, Guillaume Maurin,
Tópico(s)Carbon Dioxide Capture Technologies
ResumoA series of porous Zr oxoclusters-based MOFs was computationally explored for their gas storage/capture performances. The highly porous UiO-67(Zr) and UiO-68(Zr) solids show exceptionally high CH4 and CO2 adsorption capacities under operating conditions that make these thermal, water and mechanical resistant materials very promising for physisorption-based processes.
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