The First Transition Metal Complexes of 15-Membered Triolefinic Macrocycles: (E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-triene Complexes of Palladium(0), Platinum(0), and Silver(I)
2001; Wiley; Volume: 2001; Issue: 8 Linguagem: Inglês
10.1002/1099-0682(200108)2001
ISSN1099-0682
AutoresSílvia Cerezo, Jordi Cortès, Elena López Lago, Elı́es Molins, Marcial Moreno‐Mañas, Teodor Parella, Roser Pleixats, Javier Torrejón, Adelina Vallribera,
Tópico(s)Asymmetric Hydrogenation and Catalysis
Resumo(E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-trienes (1) form very stable complexes with Pd0 and Pt0, and moderately stable complexes with AgI. The three olefins in the macrocycle are responsible for the complexation. The X-ray structures of two complexes of Pd0 and Pt0 are presented; both complexes are planar trigonal.
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