On the Debye-Waller factor in atom-surface scattering

1982; Taylor & Francis; Volume: 45; Issue: 2 Linguagem: Inglês

10.1080/01418618208244301

ISSN

0141-8610

Autores

Nicolás García-Aracil, A. A. Maradudin, V. Celli,

Tópico(s)

Thermography and Photoacoustic Techniques

Resumo

Abstract A theory for the Debye-Waller factor in atom-surface scattering is presented, to lowest order in the phonon contributions. Multiple-scattering effects as well as the cross-correlated surface atom displacements are included. The theory accounts for experimental data without the necessity of introducing the Armand effect, which is due to the finite size of the incident atom. The work presented here implies that the Kirchhoff approximation fails when the energy of the incident particle is in the energy range of the phonon spectrum. The results of the calculation are presented in the high-temperature limit, and it is observed that the Rayleigh surface phonons contribute three-quarters of the Debye–Waller factor, while the bulk phonons account for the rest. This result is interesting because the calculation of the former contribution is simpler than that, of the latter.

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