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Reductive Selenation of Aliphatic Ketones and Aldehydes by Selenium, Carbon Monoxide, and Water Leading to Symmetrical Diselenides

1986; Taylor & Francis; Volume: 16; Issue: 9 Linguagem: Inglês

10.1080/00397918608056348

1532-2432

Yutaka Nishiyama, Sawako Hamanaka, Akiya Ogawa, Shinji Murai, Noboru Sonoda,

Chemical Synthesis and Reactions

Abstract Aliphatic ketones and aldehydes undergo reductive selenation with selenium, carbon monoxide, and water, followed by air oxidation, to give symmetrical diselenides in moderate to high yields (eq 2).