Artigo Revisado por pares

An appraisal of new variants of Dde amine protecting group for solid phase peptide synthesis

1998; Elsevier BV; Volume: 39; Issue: 12 Linguagem: Inglês

10.1016/s0040-4039(97)10828-0

ISSN

1873-3581

Autores

Siri Ram Chhabra, Bhupinder Hothi, David J. Evans, Peter D. White, Barrie W. Bycroft, Weng C. Chan,

Tópico(s)

Carbohydrate Chemistry and Synthesis

Resumo

A series of new variants of Dde, substituted at the exocyclic alkene position have been developed and their application in solid phase peptide synthesis assessed. The new derivatives offer complete resistance towards 20% piperidine in DMF and provide a considerable barrier towards N→N′-intramolecular migration.

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