Crystal Structure of [Ru(bpy) 2 (CO)( η 1 -C(O)OH)] + (bpy = 2,2′-bipyridine) as a Key Intermediate in CO 2 /CO Conversion
1996; Oxford University Press; Volume: 25; Issue: 1 Linguagem: Inglês
10.1246/cl.1996.27
ISSN1348-0715
AutoresKiyotsuna Toyohara, Hirotaka Nagao, Tomohiro Adachi, Toshikatsu Yoshida, Koji Tanaka,
Tópico(s)Metal-Organic Frameworks: Synthesis and Applications
ResumoAbstract Molecular structure of [Ru(bpy)2(CO)(η1-C(O)OH)](CF3SO3)(H2O) (bpy = 2,2′-bipyridine) has revealed that protonation of [Ru(η1-CO2)(bpy)2(CO)] as a key step in CO2/CO conversion shortens the Ru-C(O)OH bond distance compared with the Ru-CO2 one due to enhancement of dπ-pπ* interaction in the former.
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