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Recent advances in stratification and film formation of latex films; attenuated total reflection and step-scan photoacoustic FTIR spectroscopic studies

1998; Wiley; Volume: 70; Issue: 7 Linguagem: Inglês

10.1002/(sici)1097-4628(19981114)70

1097-4628

Bor-J. Niu, Marek W. Urban,

Spectroscopy and Chemometric Analyses

Journal of Applied Polymer ScienceVolume 70, Issue 7 p. 1321-1348 Research Article Recent advances in stratification and film formation of latex films; attenuated total reflection and step-scan photoacoustic FTIR spectroscopic studies Bor-J. Niu, Bor-J. Niu Department of Polymers and Coatings, North Dakota State University, Fargo, North DakotaSearch for more papers by this authorMarek W. Urban, Corresponding Author Marek W. Urban Department of Polymers and Coatings, North Dakota State University, Fargo, North DakotaDepartment of Polymers and Coatings, North Dakota State University, Fargo, North Dakota===Search for more papers by this author Bor-J. Niu, Bor-J. Niu Department of Polymers and Coatings, North Dakota State University, Fargo, North DakotaSearch for more papers by this authorMarek W. Urban, Corresponding Author Marek W. Urban Department of Polymers and Coatings, North Dakota State University, Fargo, North DakotaDepartment of Polymers and Coatings, North Dakota State University, Fargo, North Dakota===Search for more papers by this author First published: 07 December 1998 https://doi.org/10.1002/(SICI)1097-4628(19981114)70:7 3.0.CO;2-OCitations: 18AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Surfactant–latex molecular level interactions as well as transient effects during latex film formation play an important role in latex technology. This review article focuses on the siloxane effects on anionic sodium dioctylsulfosuccinate (SDOSS) surfactant exudation during latex coalescence and quantitative analysis of SDOSS distribution at the both film–air (F–A) and film–substrate (F–S) interfaces. Attenuated total reflection (ATR) Fourier transform infrared (FTIR) spectroscopy was utilized for characterization of the interactions between SDOSS and styrene–butyl acrylate latex copolymers. In addition, studies of SDOSS stratification along with depth-profiling analysis during latex film formation utilizing step-scan photoacoustic (S2-PAS) FTIR spectroscopy illustrate that SDOSS content is enriched at the F–A interface and decreases as the penetration depth increases across the latex film thickness. © 1998 John Wiley & Sons, Inc. J. Appl. Polym. Sci. 70: 1321–1348, 1998 Citing Literature Volume70, Issue714 November 1998Pages 1321-1348 RelatedInformation