An efficient conversion of keto groups into dihydroxyacetone groups: Oxidation of ethynylcarbinol intermediates by using hypervalent iodine reagent
1985; Elsevier BV; Volume: 26; Issue: 32 Linguagem: Inglês
10.1016/s0040-4039(00)89264-3
ISSN1873-3581
AutoresYasumitsu Tamura, Takayuki Yakura, Jun‐ichi Haruta, Yasuyuki Kita,
Tópico(s)Alkaloids: synthesis and pharmacology
ResumoA short and efficient synthesis of dihydroxyacetone groups from keto groups involving the oxidation of ethynylcarbinol intermediates with [bis(trifluoroacetoxy) iodo] benzene (PIFA), is described.
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