The First Isolable 4-Silatriafulvene
2002; Wiley; Volume: 41; Issue: 8 Linguagem: Inglês
10.1002/1521-3773(20020415)41
ISSN1521-3773
AutoresKenkichi Sakamoto, Jun Ogasawara, Yoshihiro Kon, Tatsuya Sunagawa, Chizuko Kabuto, Mitsuo Kira,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoUnique structural characteristics and reactivities caused by the less-polar Si−C double bond in the 4-silatriafulvene 1 were revealed by spectroscopic studies and X-ray structural analysis. Compound 1 was isolated by applying a synthetic procedure using a sila-Peterson-type reaction.
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