The infra-red spectra of some stable diazonium salts
1961; Elsevier BV; Volume: 17; Issue: 9-10 Linguagem: Inglês
10.1016/0371-1951(61)80030-1
ISSN1873-3816
AutoresR. H. Nuttall, Emmert Roberts, D. W. A. Sharp,
Tópico(s)Nonlinear Optical Materials Research
ResumoA study of the infra-red spectra of a number of diazonium salts shows that there is bonding from the anion to the cation in some of the salts. It is impossible to make a definite correlation between the N-N stretching frequency and electronic effects due to other substituents in the aromatic ring. The infra-red spectra of the p-dialkylaminobenzenediazonium and P-aminobenzenediazonium cations have been interpreted as favouring structures in which the positive charge is transferred from the diazonium group to the amine grouping.
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