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BIBTEX RIS

Nickel(0)-Catalyzed Fluoroalkylation of Alkenes, Alkynes, and Aromatics with Perfluoroalkyl Chlorides

2001; American Chemical Society; Volume: 66; Issue: 13 Linguagem: Inglês

10.1021/jo010178j

ISSN

1520-6904

Autores

Xiao‐Ting Huang, Qing‐Yun Chen,

Tópico(s)

Carbon dioxide utilization in catalysis

Resumo

Treatment of perfluoroalkyl chlorides (R(F)Cl) with alkenes, alkynes, or aromatics in the presence of 0.1 equiv of nickel dichloride, 1.5 equiv of zinc powder, and 0.4 equiv of triphenylphosphine in DMF at 95-100 degrees C for 6-8 h give the corresponding perfluoroalkylated products in good yields. A single electron-transfer mechanism is suggested.

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