Kinetic and Thermodynamic Control by Chemical Bond Rearrangement on a Si(001) Surface
2004; Wiley; Volume: 43; Issue: 11 Linguagem: Inglês
10.1002/anie.200352074
ISSN1521-3773
AutoresChiho Kataoka-Hamai, Akihiko Takagi, Masateru Taniguchi, Takuya Matsumoto, Tomoji Kawai,
Tópico(s)Semiconductor materials and interfaces
ResumoAngewandte Chemie International EditionVolume 43, Issue 11 p. 1349-1352 Communication Kinetic and Thermodynamic Control by Chemical Bond Rearrangement on a Si(001) Surface Chiho Hamai Dr., Chiho Hamai Dr. Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan, Fax: (+81) 6-6875-2440Search for more papers by this authorAkihiko Takagi Dr., Akihiko Takagi Dr. Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan, Fax: (+81) 6-6875-2440Search for more papers by this authorMasateru Taniguchi Dr., Masateru Taniguchi Dr. Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan, Fax: (+81) 6-6875-2440Search for more papers by this authorTakuya Matsumoto Dr., Takuya Matsumoto Dr. [email protected] Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan, Fax: (+81) 6-6875-2440Search for more papers by this authorTomoji Kawai Prof. Dr., Tomoji Kawai Prof. Dr. Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan, Fax: (+81) 6-6875-2440Search for more papers by this author Chiho Hamai Dr., Chiho Hamai Dr. Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan, Fax: (+81) 6-6875-2440Search for more papers by this authorAkihiko Takagi Dr., Akihiko Takagi Dr. Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan, Fax: (+81) 6-6875-2440Search for more papers by this authorMasateru Taniguchi Dr., Masateru Taniguchi Dr. Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan, Fax: (+81) 6-6875-2440Search for more papers by this authorTakuya Matsumoto Dr., Takuya Matsumoto Dr. [email protected] Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan, Fax: (+81) 6-6875-2440Search for more papers by this authorTomoji Kawai Prof. Dr., Tomoji Kawai Prof. Dr. Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan, Fax: (+81) 6-6875-2440Search for more papers by this author First published: 02 March 2004 https://doi.org/10.1002/anie.200352074Citations: 22Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Changing the force: The driving force that determines the product distribution for acetone adsorbed on the Si(001) surface can be changed from kinetic (producing a four-member-ring species; see scheme) to thermodynamic (producing the dissociation species) upon raising the surface temperature. The results show that the binding of organic molecules to the Si(001) surface is in fact reversible. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z52074_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume43, Issue11March 5, 2004Pages 1349-1352 RelatedInformation
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