Photocatalytic activity enhancement in doped titanium dioxide by crystal defects
2012; Royal Society of Chemistry; Volume: 41; Issue: 16 Linguagem: Inglês
10.1039/c2dt12018f
ISSN1477-9234
AutoresKanakkanmavudi B. Jaimy, V. P. Safeena, Swapankumar Ghosh, Neha Hebalkar, K. G. K. Warrier,
Tópico(s)Advanced Nanomaterials in Catalysis
ResumoVisible light sensitive Fe(3+) and Ce(4+) co-doped nano TiO(2) photocatalyst has been prepared by a modified aqueous sol-gel method and the activity has been measured in terms of degradation of MB dye. Both dopants shifted the absorption profile of TiO(2) to the visible region and improved activity. Fe(3+) ions trapped the charge carriers due to the stable electronic configuration and improved their separation. Ce(4+) ions, which were mainly located at the grain boundaries, cause dislocations by bending the valence and conduction bands of TiO(2) and prevent the recombination of photoexcited electrons and holes. The co-doped TiO(2) compositions exhibited higher photocatalytic activity than that of pure titania and commercially available Degussa P25 under visible light by utilising the individual and synergistic contributions of Fe(3+) and Ce(4+) dopants, respectively.
Referência(s)