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The Electrochemical Analog of the Methylene Blue Reaction: A Novel Amperometric Approach to the Detection of Hydrogen Sulfide

2000; Wiley; Volume: 12; Issue: 18 Linguagem: Inglês

10.1002/1521-4109(200012)12

1521-4109

Nathan S. Lawrence, James A. Davis, Li Jiang, T JONES, S.N. Davies, Richard G. Compton,

Advanced Chemical Sensor Technologies

ElectroanalysisVolume 12, Issue 18 p. 1453-1460 Article The Electrochemical Analog of the Methylene Blue Reaction: A Novel Amperometric Approach to the Detection of Hydrogen Sulfide Nathan S. Lawrence, Nathan S. Lawrence Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UKSearch for more papers by this authorJames Davis, James Davis Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UKSearch for more papers by this authorLi Jiang, Li Jiang Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge, CB3 0EL, UKSearch for more papers by this authorTim G. J. Jones, Tim G. J. Jones Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge, CB3 0EL, UKSearch for more papers by this authorSteve N. Davies, Steve N. Davies Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge, CB3 0EL, UKSearch for more papers by this authorRichard G. Compton, Richard G. Compton [email protected] Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UKSearch for more papers by this author Nathan S. Lawrence, Nathan S. Lawrence Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UKSearch for more papers by this authorJames Davis, James Davis Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UKSearch for more papers by this authorLi Jiang, Li Jiang Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge, CB3 0EL, UKSearch for more papers by this authorTim G. J. Jones, Tim G. J. Jones Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge, CB3 0EL, UKSearch for more papers by this authorSteve N. Davies, Steve N. Davies Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge, CB3 0EL, UKSearch for more papers by this authorRichard G. Compton, Richard G. Compton [email protected] Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UKSearch for more papers by this author First published: 18 December 2000 https://doi.org/10.1002/1521-4109(200012)12:18 3.0.CO;2-ZCitations: 161AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Abstract The electrochemical oxidation of N,N-dimethylphenylenediamine at glassy carbon electrodes in aqueous solution in the pH range 3–6 is shown to lead to currents which are considerably amplified in the presence of dissolved hydrogen sulfide. The mechanism of the electrode process is investigated and the reaction is shown to provide an attractive basis for the amperometric sensing of sulfide with an accessible range of ca. 3 to 150 μM (0.1 to 4.8 ppm). References 1 N. Miura, Y. Yang, L. Geyu, Y. Noboru, Sens. Actuators 1996, 34, 367. 2 R. S. Hannah, L. J. Hayden, S. H. Roth, Neurosci. Lett. 1989, 99, 323. 3 E. Fischer, Chem. Ber. 1883, 16, 2234. 4 W. J. Williams, Handbook of anion determination, Butterworths, London 1979, pp. 576– 580. 5 V. Kuban, P. K. Dasgupta, J. M. Marx, Anal. Chem. 1992, 64, 36. 6 A. A. Cardoso, H. L. Purnendu, K. Dasgupta, Talanta 1997, 44, 1099. 7 M. A. Spaziani, J. L. Davis, M. Tinani, M. K. Carroll, Analyst 1997, 122, 1555. 8 M. M. F. Choi, Analyst 1998, 123, 1631. 9 D. Sicilia, S. Rubio, D. Perez-Bendito, N. Maniasso, E. A. G. Zagatto, Analyst 1999, 124, 615. 10 J. Rodrigo-Fernandez, J. M. Costa, R. Pereiro, A. Sanz-Medel, Anal. Chim. Acta 1999, 398, 23. 11 G. Schiavon, G. Zotti, R. Toniolo, G. 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