Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid
2012; Elsevier BV; Volume: 50; Issue: 12 Linguagem: Inglês
10.1016/j.carbon.2012.06.002
ISSN1873-3891
AutoresYongqiang Dong, Jingwei Shao, Congqiang Chen, Hao Li, Ruixue Wang, Yuwu Chi, Xiaomei Lin, Guonan Chen,
Tópico(s)Graphene and Nanomaterials Applications
ResumoAn easy bottom–up method for the preparation of photoluminescent (PL) graphene quantum dots (GQDs) and graphene oxide (GO) has been developed by tuning the carbonization degree of citric acid and dispersing the carbonized products into alkaline solutions. The GQDs are nanosheets ∼15 nm in width, and 0.5–2.0 nm in thickness. They show a relatively strong (9.0%) PL quantum yield and an excitation-independent PL emission activity. In contrast, the GO nanostructures consist of sheets that are hundreds of nanometers in width and ∼1 nm in height. They exhibit a relatively weak (2.2%) PL quantum yield and an excitation-dependent PL emission activity.
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