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Photodimerization of a 1D hydrogen-bonded zwitter-ionic lead( ii ) complex and its isomerization in solution

2007; Royal Society of Chemistry; Issue: 4 Linguagem: Inglês

10.1039/b714355a

1364-548X

Abdul Malik P. Peedikakkal, Lip Lin Koh, Jagadese J. Vittal,

Supramolecular Chemistry and Complexes

A pair of bpe-H(+) ligands in a zwitter-ionic complex undergoes photochemical cycloaddition quantitatively accompanied by proton transfer and the cyclobutane ring isomerizes slowly in solution to two more isomers, catalyzed by CF(3)CO(2)H acid.