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Targeted synthesis of a mesoporous triptycene-derived covalent organic framework

2012; Royal Society of Chemistry; Volume: 15; Issue: 8 Linguagem: Inglês

10.1039/c2ce26487k

1466-8033

Zafer Kahveci, Timur İslamoğlu, Ghulam Abbas Shar, Ransheng Ding, Hani M. El‐Kaderi,

Luminescence and Fluorescent Materials

The synthesis and characterization of a highly porous triptycene-derived covalent organic framework (TDCOF-5) and its performance in small gas storage are reported. TDCOF-5 crystallizes into a 2D mesoporous network that contains accessible boron sites, exhibits high surface area (SALang = 3832 m2 g−1), and high gas uptake under low pressure settings.