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Synthese von mono[tris(trimethylsilyl)cyclopentadienyl]-eisen-komplexen

1987; Elsevier BV; Volume: 333; Issue: 3 Linguagem: Inglês

10.1016/s0022-328x(00)99818-8

1872-8561

Jun Okuda,

Synthesis and characterization of novel inorganic/organometallic compounds

The reaction of ferrous halides FeX2 (X  Cl, Br, I) with tris(trimethylsilyl)cyclopentadienyllithium [η5-C5H2(SiMe3)3-1,2,4]Li in THF at −95°C leads to the formation of reactive intermediates which can be trapped with CO to give pentanesoluble dicarbonylhalo complexes [η5-C5H2(SiMe3)3-1,2,4]Fe(CO)2X in good yields.