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BIBTEX RIS

Do all ionic liquids need organic cations? Characterisation of [AlCl2·nAmide]+ AlCl4− and comparison with imidazolium based systems

2011; Royal Society of Chemistry; Volume: 47; Issue: 12 Linguagem: Inglês

10.1039/c0cc04989a

ISSN

1364-548X

Autores

Hadi M. A. Abood, Andrew P. Abbott, Andrew D. Ballantyne, Karl S. Ryder,

Tópico(s)

Inorganic and Organometallic Chemistry

Resumo

The addition of a simple amide to AlCl(3) causes the formation of a liquid of the form [AlCl(2)·nAmide](+) AlCl(4)(-). The material thus produced is liquid over a wide temperature range, is relatively insensitive to water and has the properties of an ionic liquid. This ionic liquid is shown to be a suitable medium for the acetylation of ferrocene and the electrodeposition of aluminium and demonstrated that quaternary ammonium cations are not always needed to form ionic liquids.

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