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Au–TiO2/Chit modified sensor for electrochemical detection of trace organophosphates insecticides

2008; Elsevier BV; Volume: 76; Issue: 4 Linguagem: Inglês

10.1016/j.talanta.2008.04.045

1873-3573

Ying Qu, Hyun Min, Yanqiang Wei, Fan Xiao, G. Shi, Xinle Li, Ling Jin,

Analytical Chemistry and Sensors

In this paper, Au–TiO2/Chit modified electrode was prepared with Au–TiO2 nanocomposite (Au–TiO2) and Chitosan (Chit) as a conjunct. The Au–TiO2 nanocomposite and the films were characterized by electrochemical and spectroscopy methods. A set of experimental conditions was also optimized for the film's fabrication. The electrochemical and electrocatalytic behaviors of Au–TiO2/Chit modified electrode to trace organophosphates (OPs) insecticides such as parathion were discussed in this work. By differential pulse voltammetry (DPV) measurement, the current responses of Au–TiO2/Chit modified electrode were linear with parathion concentration ranging from 1.0 ng/ml to 7.0 × 103 ng/ml with the detection limit of 0.5 ng/ml. In order to evaluate the performance of the detection system, we also examined the real samples successfully in this work. It exhibited a sensitive, rapid and easy-to-use method for the fast determination of trace OPs insecticides.