Supramolecular Catalysis in the Organic Solid State through Dry Grinding
2010; Wiley; Volume: 49; Issue: 25 Linguagem: Inglês
10.1002/anie.201000874
ISSN1521-3773
AutoresAnatoliy N. Sokolov, Dejan‐Krešimir Bučar, Jonas Baltrušaitis, Sean X. Gu, Leonard R. MacGillivray,
Tópico(s)Building materials and conservation
ResumoChemical mechanics: Hydrogen-bond-driven self-assembly and mechanochemistry are used to facilitate supramolecular catalysis in the solid state. Mortar-and-pestle grinding proves to be an efficient means to achieve co-crystal formation and turnover using a physical mixture composed of an olefin and catalytic amounts of a ditopic template (see scheme).
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