Artigo Revisado por pares

Supramolecular Catalysis in the Organic Solid State through Dry Grinding

2010; Wiley; Volume: 49; Issue: 25 Linguagem: Inglês

10.1002/anie.201000874

ISSN

1521-3773

Autores

Anatoliy N. Sokolov, Dejan‐Krešimir Bučar, Jonas Baltrušaitis, Sean X. Gu, Leonard R. MacGillivray,

Tópico(s)

Building materials and conservation

Resumo

Chemical mechanics: Hydrogen-bond-driven self-assembly and mechanochemistry are used to facilitate supramolecular catalysis in the solid state. Mortar-and-pestle grinding proves to be an efficient means to achieve co-crystal formation and turnover using a physical mixture composed of an olefin and catalytic amounts of a ditopic template (see scheme).

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