Novel Cu(iii) bis-1,2-diselenolene complex with a highly extended 3D framework through Na+ coordination
2002; Royal Society of Chemistry; Volume: 4; Issue: 93 Linguagem: Inglês
10.1039/b209330h
ISSN1466-8033
AutoresXavi Ribas, Jo�o Dias, Jorge Morgado, Klaus Wurst, Manuel Almeida, Jaume Veciana, Concepci� Rovira,
Tópico(s)Metal-Organic Frameworks: Synthesis and Applications
ResumoThe crystal structure of a new Cu(III) complex with the ligand pds2− (pds, pyrazine-2,3-diselenolate) shows a unique packing pattern with segregated stacks of complex molecules interconnected through the pyrazine N coordination to Na counterions, which complete their coordination environment with four water molecules.
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