Sila pummerer rearrangement in highly sterically hindered organosilicon compounds: A new route to bis(trimethylsilyl)ketone
1986; Elsevier BV; Volume: 27; Issue: 49 Linguagem: Inglês
10.1016/s0040-4039(00)85379-4
ISSN1873-3581
AutoresAlfredo Ricci, Alessandro Degl’Innocenti, Monica Ancillotti, Giancarlo Seconi, Pasquale Dembech,
Tópico(s)Polyoxometalates: Synthesis and Applications
ResumoThe oxidation of the tris(trimethylsi]yl)methylthio-methane with m-chloroperoxybenzoic acid, leads through a sila-Pummerer rearrangement occurring in unusually mild conditions, to bis(trimethylsilyl)ketone.
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