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III. On the action of nitric acid and of binoxide of manganese and sulphuric acid on the organic bases

1859; Royal Society; Volume: 9; Linguagem: Inglês

10.1098/rspl.1857.0126

2053-9126

Augustus Matthiessen,

Boron Compounds in Chemistry

In the Proceedings of the Royal Society (vol. ix. p. 118), I stated that by the action of nitrous acid on aniline I had obtained ammonia and nitrophenasic acid; since then I have acted on several other of the organic bases with the same reagent, as well as with nitric acid, and with binoxide of manganese and sulphuric acid; and I will now shortly enumerate the experiments. 1. Action of Nitrous Acid on Amylaniline. The dilute solution of the nitrate of amylaniline was acted on by nitrous acid at 100° C. for 12 hours. Amylaniline and ammonia were obtained, but in quantities too small to be quantitatively determined.