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Catalytic oxidation of hydrogen chloride in a fluid bed reactor

1973; Wiley; Volume: 19; Issue: 5 Linguagem: Inglês

10.1002/aic.690190518

1547-5905

Shintaro Furusaki,

Nonlinear Dynamics and Pattern Formation

Abstract The Deacon reaction (HCI + 1/4 O 2 ⇋ 1/2 Cl 2 + 1/2 H 2 O) was studied in a catalytic fluid bed reactor. Reaction rates found from measurements in differential and integral reactors were represented by the Langmuir‐Hinshelwood type rate equation. Considering the effect of catalysts in the dilute phase, it was found that conversions in a fluid bed reactor can be calculated without any modifying parameters. It is pointed out that the wake fraction, which has been necessary to consider for fast reactions in a fluid bed reactor, is attributed to the dilute phase effect.