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In‐Operando Neutron Diffraction Studies of Transition Metal Hydrogen Storage Materials

2012; Wiley; Volume: 3; Issue: 1 Linguagem: Inglês

10.1002/aenm.201200390

1614-6840

Kazuya Kamazawa, Masakazu Aoki, Tatsuo Noritake, Kazutoshi Miwa, Jun Sugiyama, Shin‐ichi Towata, Mamoru Ishikiriyama, Samantha K. Callear, Martin O. Jones, William I. F. David,

Ammonia Synthesis and Nitrogen Reduction

Advanced Energy MaterialsVolume 3, Issue 1 p. 39-42 Communication In-Operando Neutron Diffraction Studies of Transition Metal Hydrogen Storage Materials Kazuya Kamazawa, Kazuya Kamazawa Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, Japan J-PARC Center, Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195, JapanSearch for more papers by this authorMasakazu Aoki, Masakazu Aoki Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, JapanSearch for more papers by this authorTatsuo Noritake, Tatsuo Noritake Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, JapanSearch for more papers by this authorKazutoshi Miwa, Kazutoshi Miwa Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, JapanSearch for more papers by this authorJun Sugiyama, Jun Sugiyama Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, JapanSearch for more papers by this authorShin-ichi Towata, Corresponding Author Shin-ichi Towata e0472@mosk.tytlabs.co.jp Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, Japan Shin-ichi Towata, Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, Japan William I. F. David, ISIS Facility, STFC, Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, UK.Search for more papers by this authorMamoru Ishikiriyama, Mamoru Ishikiriyama Advanced Material Engineering Division, TOYOTA MOTOR CORPORATION, Higashi-fuji Technical Center, JapanSearch for more papers by this authorSamantha K. Callear, Samantha K. Callear ISIS Facility, STFC, Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, UKSearch for more papers by this authorMartin O. Jones, Martin O. Jones ISIS Facility, STFC, Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, UK Inorganic Chemistry Laboratory, South Parks Road, University of Oxford, Oxford, OX1 3QR, UKSearch for more papers by this authorWilliam I. F. David, Corresponding Author William I. F. David Bill.David@stfc.ac.uk ISIS Facility, STFC, Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, UK Inorganic Chemistry Laboratory, South Parks Road, University of Oxford, Oxford, OX1 3QR, UK Shin-ichi Towata, Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, Japan William I. F. David, ISIS Facility, STFC, Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, UK.Search for more papers by this author Kazuya Kamazawa, Kazuya Kamazawa Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, Japan J-PARC Center, Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195, JapanSearch for more papers by this authorMasakazu Aoki, Masakazu Aoki Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, JapanSearch for more papers by this authorTatsuo Noritake, Tatsuo Noritake Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, JapanSearch for more papers by this authorKazutoshi Miwa, Kazutoshi Miwa Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, JapanSearch for more papers by this authorJun Sugiyama, Jun Sugiyama Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, JapanSearch for more papers by this authorShin-ichi Towata, Corresponding Author Shin-ichi Towata e0472@mosk.tytlabs.co.jp Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, Japan Shin-ichi Towata, Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, Japan William I. F. David, ISIS Facility, STFC, Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, UK.Search for more papers by this authorMamoru Ishikiriyama, Mamoru Ishikiriyama Advanced Material Engineering Division, TOYOTA MOTOR CORPORATION, Higashi-fuji Technical Center, JapanSearch for more papers by this authorSamantha K. Callear, Samantha K. Callear ISIS Facility, STFC, Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, UKSearch for more papers by this authorMartin O. Jones, Martin O. Jones ISIS Facility, STFC, Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, UK Inorganic Chemistry Laboratory, South Parks Road, University of Oxford, Oxford, OX1 3QR, UKSearch for more papers by this authorWilliam I. F. David, Corresponding Author William I. F. David Bill.David@stfc.ac.uk ISIS Facility, STFC, Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, UK Inorganic Chemistry Laboratory, South Parks Road, University of Oxford, Oxford, OX1 3QR, UK Shin-ichi Towata, Toyota Central Research and Development, Laboratories Inc., Nagakute, Aichi 480-1192, Japan William I. F. David, ISIS Facility, STFC, Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX11 0QX, UK.Search for more papers by this author First published: 13 September 2012 https://doi.org/10.1002/aenm.201200390Citations: 6Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Neutron diffraction studies of hydrogen absorption and desorption (non-isotopically enriched) in the metal hydride Ti25Cr50V20Mo5Hx, reveal the origin of the reduction in capacity exhibited by this material on cycling. The sequestered hydrogen is principally located in the octahedral and tetrahedral interstitial sites in the basal plane, while local diffusion along the unique tetragonal axis appears to be preferred. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description aenm_201200390_sm_suppl.pdf195.3 KB suppl Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume3, Issue1January, 2013Pages 39-42 RelatedInformation