Artigo Revisado por pares

A linear single-molecule magnet based on [RuIII(CN)6]3−

2011; Royal Society of Chemistry; Volume: 47; Issue: 24 Linguagem: Inglês

10.1039/c1cc12158h

ISSN

1364-548X

Autores

Kasper S. Pedersen, Jan Dreiser, Joscha Nehrkorn, Maren Gysler, Magnus Schau‐Magnussen, Alexander Schnegg, K. Holldack, Robert Bittl, Stergios Piligkos, Høgni Weihe, Philip L. W. Tregenna‐Piggott, O. Waldmann, Jesper Bendix,

Tópico(s)

Porphyrin and Phthalocyanine Chemistry

Resumo

We report the synthesis, structure and magnetic properties of the first molecular cluster and single-molecule magnet to incorporate [Ru(III)(CN)(6)](3-). Frequency-domain Fourier-transform THz-EPR (FDFT THz-EPR) and magnetic susceptibility measurements indicate strongly anisotropic Mn-Ru exchange interactions.

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