A linear single-molecule magnet based on [RuIII(CN)6]3−
2011; Royal Society of Chemistry; Volume: 47; Issue: 24 Linguagem: Inglês
10.1039/c1cc12158h
ISSN1364-548X
AutoresKasper S. Pedersen, Jan Dreiser, Joscha Nehrkorn, Maren Gysler, Magnus Schau‐Magnussen, Alexander Schnegg, K. Holldack, Robert Bittl, Stergios Piligkos, Høgni Weihe, Philip L. W. Tregenna‐Piggott, O. Waldmann, Jesper Bendix,
Tópico(s)Porphyrin and Phthalocyanine Chemistry
ResumoWe report the synthesis, structure and magnetic properties of the first molecular cluster and single-molecule magnet to incorporate [Ru(III)(CN)(6)](3-). Frequency-domain Fourier-transform THz-EPR (FDFT THz-EPR) and magnetic susceptibility measurements indicate strongly anisotropic Mn-Ru exchange interactions.
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