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MICHAEL ADDITION-PETERSON OLEFINATION SEQUENCE OF METHYL 2-(TRIMETHYLSILYL)ACRYLATE AS A CONVENIENT METHOD FOR CONSECUTIVE FORMATION OF CARBON-CARBON SINGLE AND DOUBLE BONDS

1984; Oxford University Press; Volume: 13; Issue: 11 Linguagem: Inglês

10.1246/cl.1984.1993

1348-0715

Otohiko Tsuge, Shuji Kanemasa, Yusuke Ninomiya,

Inorganic and Organometallic Chemistry

Abstract A convenient method for the consecutive formation of carbon–carbon single and double bonds is presented with the example of the Peterson olefination of the carbanions resulted from the Michael addition of organometallics to methyl 2-(trimethylsilyl)acrylate.